dustinquiz181 dustinquiz181
  • 20-11-2020
  • Chemistry
contestada

What are the signs of ΔH, ΔS, and ΔG for the spontaneous conversion of a crystalline solid into a gas?

Respuesta :

ibiscollingwood ibiscollingwood
  • 23-11-2020

Answer:

ΔH>0, ΔS>0, and ΔG<0

Explanation:

Crystalline solid → Gas

  • ΔG < 0 T  as the reaction is Spontaneous
  • The solid is converted into gas so the Entropy will increase as randomness is more in gas than solid, ΔS > 0

using Gibbs equation

ΔG = ΔH - TΔS

as ΔG < 0 and ΔS > 0

ΔH - TΔS <0

ΔH < TΔS ⇒ΔH >0

This gives that ΔH will be Positive but it will be less than TΔS. So we need to provide some energy to convert crystalline solid into gas.

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